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1 article(s) from Yusubov, Мekhman S

Synthesis of polydicyclopentadiene using the Cp₂TiCl₂/Et₂AlCl catalytic system and thin-layer oxidation of the polymer in air

Zhargolma B. Bazarova,
Ludmila S. Soroka,
Alex A. Lyapkov,
Мekhman S. Yusubov and
Francis Verpoort

Beilstein J. Org. Chem. 2019, 15, 733–745, doi:10.3762/bjoc.15.69

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Graphical Abstract

Figure 1: Absorption spectra in the UV and visible spectral region: 1) bis(cyclopentadienyl)titan dichloride (...

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Figure 2: Absorption spectra in the visible spectral region: 1) Cp₂TiCl₂·AlEt₂Cl (toluene, 10 mmol/L, Ti/Al r...

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Figure 3: ¹Н NMR spectra of tricyclopentadiene (a) and the interaction product between Cp₂TiCl₂ and AlEt₂Cl w...

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Scheme 1: Mechanism of alkylation of Cp₂TiCl₂.

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Figure 4: Visible spectra of a mixture of Cp₂TiCl₂ and AlEt₂Cl as function of time.

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Figure 5: Thermometric curve of DCPD polymerization using the catalyst system based on Cp₂TiCl₂ (a) and its s...

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Scheme 2: The structures formed as a result of the cationic polymerization of dicyclopentadiene.

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Scheme 3: The units resulting from ROMP of dicyclopentadiene.

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Scheme 4: Mechanism of ROMP dicyclopentadiene.

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Figure 6: FTIR spectrum of PDCPD obtained in toluene with the catalyst system based on Cp₂TiCl₂ and AlEt₂Cl.

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Figure 7: ¹Н NMR spectrum of PDCPD obtained with the catalytic system based on Cp₂TiCl₂ and AlEt₂Cl.

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Figure 8: GPC traces for two samples of DCPD polymers obtained at a concentration of Cp₂TiCl₂/AlEt₂Cl complex...

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Figure 9: IR spectra of cationic polymerized dicyclopentadiene taken after certain periods of time exposed to...

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Figure 10: Correlation of intensities of vibrational bands at 1620 and 700 cm⁻¹ and layer exposure time in air...

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Figure 11: DSC exotherm for PDCPD subjected to air oxidation for 700 hours.

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Figure 12: DSC exotherm for PDCPD subjected to unexposed film: 1) in air atmosphere; 2) in argon.

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Scheme 5: Possible radical formation in the reaction (1).

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Scheme 6: The first step of the chain propagation.

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Figure 13: Dependence of intensities of adsorption bands at 1410 and 700 cm⁻¹ and dwell time of the layer in a...

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Figure 14: Semi-logarithmic kinetic curve of PDCPD oxidation in air (thin layer on silicon) with respect to in...

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Figure 15: The distribution of oxygen concentration in the polymer layer: 1 – a layer of oxidized cross-linked...

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Figure 16: Dependence of the ratio of adsorption bands at 1700 and 700 cm⁻¹ on the exposure time of the layer ...

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Figure 17: Infrared spectra (a) of products of cationic polymerization of DCPD, stabilized with an antioxidant...

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Published 20 Mar 2019

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Synthesis of polydicyclopentadiene using the Cp2TiCl2/Et2AlCl catalytic system and thin-layer oxidation of the polymer in air

Synthesis of polydicyclopentadiene using the Cp₂TiCl₂/Et₂AlCl catalytic system and thin-layer oxidation of the polymer in air